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The Advances in Chemical Physics sequence presents the chemical physics box with a discussion board for serious, authoritative reviews of advances in each quarter of the self-discipline. quantity 121 comprises the most recent learn on polymer melts at reliable surfaces, infrared lineshapes of susceptible hydrogen bonds, ab initio quantum molecular dynamics, and plenty of different topics.
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Phe-a mutant case have absorption spectra at various temperatures so far been available. Although the absorption spectra of the WT and R26 mutant RCs are available at a few temperatures like 1 K, 4 K, 77 K, and 298 K, the analyzed results are not so consistent (see Table III). 22 The angle between ~ me1 g and ~ me2 g in different model also shown for comparison. From Ref. 39. 24 s. h. lin et al. methods of RCs and the experimental conditions are somewhat different for different groups. Thus, to examine validity of the electronic state model and the thermal expansion model presented in this work, absorption spectra experiments of each RC at various temperatures should be carefully performed.
In other words, vibrational modes can be classiﬁed into promoting and accepting modes. f ¼ X X Y 2p o‘ 0 0 0 0 jR‘ ðfiÞj2 Pi jhwf 0j jwij ij2 h 2"h " j 0 0 0 Â ½" ‘ dðÀ" ho‘ þ Ef0 0 À Ei Þ þ ð" ‘ þ 1Þdð"ho‘ þ Ef0 0 À Ei Þ ð3:76Þ For the displaced oscillator model, Eq. f ¼ ð1 1 o‘ 2 jR ð fiÞj dteitofi ½" ‘ eÀito‘ þ ð" ‘ þ 1Þeito‘ ‘ h h2 2" " À1 " # X Àitoj itoj 0 Â exp À Sj fð2" nj þ 1Þ À " nj e À ð"nj þ 1Þe g ð3:77Þ j It should be noted that usually " ho‘ =kT ) 1; at this limit, Eq.
Lin et al. 0438 Angles (degrees) between the transition moments of the special pair dimer. Angles of the transition moments with the membrane normal. peak ratios j~ me1 g j2 =j~ me2 g j2 , j~ me3 g j2 =j~ me2 g j2 , and j~ me4 g j2 =j~ me2 g j2 , they are found to simultaneously agree with the values presented in Table III. Table IV lists the calculation results of the delocalized model, including the angles between any two Bchls and the transition dipole moment intensity ratios j~ me1 g j2 =j~ m e2 g j 2 , 2 2 2 2 me2 g j , and j~ me4 g j =j~ me2 g j at various temperatures.