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50, 2919 (1940). ELECTRODES FOR CONDUCTANCE MEASUREMENTS 35 due to capacity and interaction effects, but these can be largely eliminated by suitable grounding and shielding (see p. 42). C. C. galvanometer is a A combination of a vacuum-tube, or other form satisfactory detector. C. rectifier, and a direct current galvanometer has been employed, FIG. 11. and in some Vacuum-tube amplifier cases the thermal effect of the alternating current has been and a sensitive galvanometer, used, in conjunction with a thermocouple for detection purposes.
7, I. The resistance II I FIG. 7. Calculation of specific resistance of the bar is seen to be equivalent to that of / layers, such as the one depicted in Fig. 7, II, in series with one another; further, each layer is equivalent to a cubes, each of one cm. side, whoso resistances are in If p is the resistance, in ohms, of a centimeter cube, generally parallel. called the specific resistance of the substance constituting the conductor, the resistance r of the layer containing the a cubes is given by there being a terms on the right-hand side: r it P ~~~ If R is the resistance of the whole bar, which each of resistance r in series, then R = Ir = follows, therefore, that p - ohms.
If corks are used they should be covered with tin foil to prevent direct contact with water or steam. Non-aqueous solvents should be purified by careful distillation, special care being taken to eliminate all traces of moisture. Not only are conductances in water appreciably different from those in non-aqueous media, but in certain cases, particularly if the electrolytic solution contains hydrogen, hydroxyl or alkoxyl ions, small quantities of water have a very considerable effect on the conductance.